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Material classes are practical database groupings rather than strict electronic-structure labels. Mixed-valence and phase-change oxides are grouped with semiconducting/oxide materials unless primarily used as metallic conductors.

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Candidate models at selected N

Optical constants and model response

Use the plot-quantity selector to switch between optical constants and permittivity. Filled markers show experimental database points; optional open markers show the fitting grid.

Mathematical model definitions

PoleResidue JSON / rational-pole (RP)

εJSON(ω) = ε − ∑m=1M [ cm/(iω + am) + cm*/(iω + am*) ], Re(am) < 0.

This is the native convention used by the exported JSON files and the MATLAB reference code, under the exp(−iωt) time convention. Here am and cm are the pole and residue stored in the JSON file; passive poles have negative real parts and should not be sign-flipped.

Critical-point fitting ansatz (CP)

εCP+(ω) = ε + ∑ℓ=1NCP A exp(iφ) [(Ω − ω) − iΓ]−p, ω > 0, Γ > 0.

Ω, Γ, A, φ, and p denote the critical-point energy, broadening, strength, phase, and line-shape exponent. The CP expression is used as a fitting ansatz only.

Released CP-family entries are converted to the same finite PoleResidue JSON convention used above: εJSON(ω) = ε − ∑m [cm/(iω+am) + cm*/(iω+am*)], with Re(am) < 0. The fractional-power CP term is not stored directly as the FDTD update model.

Record metadata

      

Experimental data source